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Volume 3

Volume 3 - 2007

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Article Type All...Full Research PaperPreliminary CommunicationEditorialBook ReportReviewCommentary

Table of Contents

35

Full Research Paper

11

Preliminary Communication

2

Review

2

Editorial

Overview

Large- scale ruthenium- and enzyme- catalyzed dynamic kinetic resolution of (rac)-1-phenylethanol

Krisztián Bogár, Belén Martín-Matute, Jan-E. Bäckvall

Beilstein J. Org. Chem. 2007, 3, No. 50 - published 20 Dec 2007

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Synthesis of crispine A analogues via an intramolecular Schmidt reaction

Ajoy Kapat, Ponminor Senthil Kumar, Sundarababu Baskaran

Beilstein J. Org. Chem. 2007, 3, No. 49 - published 19 Dec 2007

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Desymmetrization of 7-azabicycloalkenes by tandem olefin metathesis for the preparation of natural product scaffolds

Wolfgang Maison, Marina Büchert, Nina Deppermann

Beilstein J. Org. Chem. 2007, 3, No. 48 - published 18 Dec 2007

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Part 3. Triethylborane- air: a suitable initiator for intermolecular radical additions of S-2-oxoalkyl- thionocarbonates (S-xanthates) to olefins

Jean Boivin, Van Tai Nguyen

Beilstein J. Org. Chem. 2007, 3, No. 47 - published 13 Dec 2007

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Part 2. Mechanistic aspects of the reduction of S-alkyl- thionocarbonates in the presence of triethylborane and air

Florent Allais, Jean Boivin, Van Tai Nguyen

Beilstein J. Org. Chem. 2007, 3, No. 46 - published 12 Dec 2007

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Part 1. Reduction of S-alkyl- thionocarbonates and related compounds in the presence of trialkylboranes/air

Jean Boivin, Van Tai Nguyen

Beilstein J. Org. Chem. 2007, 3, No. 45 - published 12 Dec 2007

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Synthesis of densely functionalized enantiopure indolizidines by ring- closing metathesis (RCM) of hydroxylamines from carbohydrate- derived nitrones

Marco Bonanni, Marco Marradi, Francesca Cardona, Stefano Cicchi, Andrea Goti

Beilstein J. Org. Chem. 2007, 3, No. 44 - published 12 Dec 2007

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The tert- amino effect in heterocyclic chemistry: Synthesis of new fused pyrazolinoquinolizine and 1,4-oxazinopyrazoline derivatives

Dipak Prajapati, Kalyan Jyoti Borah

Beilstein J. Org. Chem. 2007, 3, No. 43 - published 12 Dec 2007

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Synthesis of the Benzo- fused Indolizidine Alkaloid Mimics

Daniel L. Comins, Kazuhiro Higuchi

Beilstein J. Org. Chem. 2007, 3, No. 42 - published 30 Nov 2007

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A divergent asymmetric approach to aza-spiropyran derivative and (1S,8aR)-1-hydroxyindolizidine

Jian-Feng Zheng, Wen Chen, Su-Yu Huang, Jian-Liang Ye, Pei-Qiang Huang

Beilstein J. Org. Chem. 2007, 3, No. 41 - published 08 Nov 2007

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N-1 regioselective Michael- type addition of 5-substituted uracils to (2-hydroxyethyl) acrylate

Sławomir Boncel, Dominika Osyda, Krzysztof Z. Walczak

Beilstein J. Org. Chem. 2007, 3, No. 40 - published 08 Nov 2007

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The enantiospecific synthesis of (+)-monomorine I using a 5-endo- trig cyclisation strategy

Malcolm B. Berry, Donald Craig, Philip S. Jones, Gareth J. Rowlands

Beilstein J. Org. Chem. 2007, 3, No. 39 - published 08 Nov 2007

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Vinylogous Mukaiyama aldol reactions with 4-oxy-2-trimethylsilyloxypyrroles: relevance to castanospermine synthesis

Roger Hunter, Sophie C. M. Rees-Jones, Hong Su

Beilstein J. Org. Chem. 2007, 3, No. 38 - published 03 Nov 2007

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An asymmetric synthesis of all stereoisomers of piclavines A1-4 using an iterative asymmetric dihydroxylation

Yukako Saito, Naoki Okamoto, Hiroki Takahata

Beilstein J. Org. Chem. 2007, 3, No. 37 - published 29 Oct 2007

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Electronic differentiation competes with transition state sensitivity in palladium- catalyzed allylic substitutions

Dominik A. Lange, Bernd Goldfuss

Beilstein J. Org. Chem. 2007, 3, No. 36 - published 26 Oct 2007

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Transition- metal/Lewis acid free synthesis of acyl benzothiophenes via C-C bond forming reaction

Sarbani Pal, Mohammad Ashrafuddin Khan, P. Bindu, P. K. Dubey

Beilstein J. Org. Chem. 2007, 3, No. 35 - published 25 Oct 2007

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Single and double stereoselective fluorination of (E)-allylsilanes

Marcin Sawicki, Angela Kwok, Matthew Tredwell, Véronique Gouverneur

Beilstein J. Org. Chem. 2007, 3, No. 34 - published 25 Oct 2007

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The use of chiral lithium amides in the desymmetrisation of N-trialkylsilyl dimethyl sulfoximines

Matthew J. McGrath, Carsten Bolm

Beilstein J. Org. Chem. 2007, 3, No. 33 - published 16 Oct 2007

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Additions & Corrections

A convenient allylsilane- N-acyliminium route toward indolizidine and quinolizidine alkaloids

Roland Remuson

Beilstein J. Org. Chem. 2007, 3, No. 32 - published 02 Oct 2007

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Aroylketene dithioacetal chemistry: facile synthesis of 4-aroyl- 3-methylsulfanyl- 2-tosylpyrroles from aroylketene dithioacetals and TosMIC

H. Surya Prakash Rao, S. Sivakumar

Beilstein J. Org. Chem. 2007, 3, No. 31 - published 28 Sep 2007

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Flexible synthesis of poison- frog alkaloids of the 5,8-disubstituted indolizidine- class. II: Synthesis of (-)-209B, (-)-231C, (-)-233D, (-)-235B", (-)-221I, and an epimer of 193E and pharmacological effects at neuronal nicotinic acetylcholine receptors

Soushi Kobayashi, Naoki Toyooka, Dejun Zhou, Hiroshi Tsuneki, Tsutomu Wada, Toshiyasu Sasaoka, Hideki Sakai, Hideo Nemoto, H. Martin Garraffo, Thomas F. Spande, John W. Daly

Beilstein J. Org. Chem. 2007, 3, No. 30 - published 28 Sep 2007

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Flexible synthetic routes to poison- frog alkaloids of the 5,8-disubstituted indolizidine- class I: synthesis of common lactam chiral building blocks and application to the synthesis of (-)-203A, (-)-205A, and (-)-219F

Naoki Toyooka, Dejun Zhou, Hideo Nemoto, H. Martin Garraffo, Thomas F. Spande, John W. Daly

Beilstein J. Org. Chem. 2007, 3, No. 29 - published 28 Sep 2007

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Reactions of glycidyl derivatives with ambident nucleophiles; part 2: amino acid derivatives

Gerald Dyker, Andreas Thöne, Gerald Henkel

Beilstein J. Org. Chem. 2007, 3, No. 28 - published 27 Sep 2007

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Indolizidines and quinolizidines: natural products and beyond

Joseph P. Michael

Beilstein J. Org. Chem. 2007, 3, No. 27 - published 26 Sep 2007

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Solvent- controlled regioselective protection of allyl- 4,6-benzylidene glucopyranosides

Kerry Ann Ness, Marie E. Migaud

Beilstein J. Org. Chem. 2007, 3, No. 26 - published 26 Sep 2007

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Synthesis of sulfonimidamides from sulfinamides by oxidation with N-chlorosuccinimide

Olga García Mancheño, Carsten Bolm

Beilstein J. Org. Chem. 2007, 3, No. 25 - published 25 Sep 2007

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The first organocatalytic carbonyl- ene reaction: isomerisation- free C-C bond formations catalysed by H-bonding thio- ureas

Matthew L. Clarke, Charlotte E. S. Jones, Marcia B. France

Beilstein J. Org. Chem. 2007, 3, No. 24 - published 14 Sep 2007

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Development of potential manufacturing routes for substituted thiophenes – Preparation of halogenated 2-thiophenecarboxylic acid derivatives as building blocks for a new family of 2,6-dihaloaryl 1,2,4-triazole insecticides

John W. Hull Jr., Duane R. Romer, David E. Podhorez, Mezzie L. Ash, Christine H. Brady

Beilstein J. Org. Chem. 2007, 3, No. 23 - published 04 Sep 2007

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Expedient syntheses of the N-heterocyclic carbene precursor imidazolium salts IPr·HCl, IMes·HCl and IXy·HCl

Lukas Hintermann

Beilstein J. Org. Chem. 2007, 3, No. 22 - published 28 Aug 2007

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The use of silicon- based tethers for the Pauson- Khand reaction

Adrian P. Dobbs, Ian J. Miller, Saša Martinović

Beilstein J. Org. Chem. 2007, 3, No. 21 - published 06 Jul 2007

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Novel base catalysed rearrangement of sultone oximes to 1,2-benzisoxazole- 3-methane sulfonate derivatives

Veera Reddy Arava, Udaya Bhaskara Rao Siripalli, Vaishali Nadkarni, Rajendiran Chinnapillai

Beilstein J. Org. Chem. 2007, 3, No. 20 - published 08 Jun 2007

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m-Iodosylbenzoic acid – a convenient recyclable reagent for highly efficient aromatic iodinations

Andreas Kirschning, Mekhman S. Yusubov, Roza Y. Yusubova, Ki-Whan Chi, Joo Y. Park

Beilstein J. Org. Chem. 2007, 3, No. 19 - published 04 Jun 2007

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A convenient catalyst system for microwave accelerated cross- coupling of a range of aryl boronic acids with aryl chlorides

Matthew L. Clarke, Marcia B. France, Jose A. Fuentes, Edward J. Milton, Geoffrey J. Roff

Beilstein J. Org. Chem. 2007, 3, No. 18 - published 30 May 2007

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A hydrogen- bonded channel structure formed by a complex of uracil and melamine

Reji Thomas, G. U. Kulkarni

Beilstein J. Org. Chem. 2007, 3, No. 17 - published 23 May 2007

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Allylsilanes in the synthesis of three to seven membered rings: the silylcuprate strategy

Asunción Barbero, Francisco J. Pulido, M. Carmen Sañudo

Beilstein J. Org. Chem. 2007, 3, No. 16 - published 22 May 2007

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An easy synthesis of 5-functionally substituted ethyl 4-amino- 1-aryl- pyrazolo- 3-carboxylates: interesting precursors to sildenafil analogues

Said A. S. Ghozlan, Khadija O. Badahdah, Ismail A. Abdelhamid

Beilstein J. Org. Chem. 2007, 3, No. 15 - published 01 May 2007

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Synthesis of spiropyrans: H-abstractions in 3-cycloalkenyloxybenzopyrans

Satish C. Gupta, Mandeep Thakur, Somesh Sharma, Urmila Berar, Surinder Berar, Ramesh C. Kamboj

Beilstein J. Org. Chem. 2007, 3, No. 14 - published 21 Mar 2007

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An improved synthesis of 1,3,5-triaryl- 2-pyrazolines in acetic acid aqueous solution under ultrasound irradiation

Ji-Tai Li, Xiao-Hui Zhang, Zhi-Ping Lin

Beilstein J. Org. Chem. 2007, 3, No. 13 - published 21 Mar 2007

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2-Arylhydrazononitriles as building blocks in heterocyclic synthesis: A novel route to 2-substituted- 1,2,3-triazoles and 1,2,3-triazolo[4,5-b]pyridines

Saleh M. Al-Mousawi, Moustafa Sh. Moustafa

Beilstein J. Org. Chem. 2007, 3, No. 12 - published 13 Mar 2007

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Microwave assisted synthesis of triazoloquinazolinones and benzimidazoquinazolinones

Aboul-Fetouh E. Mourad, Ashraf A. Aly, Hassan H. Farag, Eman A. Beshr

Beilstein J. Org. Chem. 2007, 3, No. 11 - published 05 Mar 2007

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Variations in product in reactions of naphthoquinone with primary amines

Marjit W. Singh, Anirban Karmakar, Nilotpal Barooah, Jubaraj B. Baruah

Beilstein J. Org. Chem. 2007, 3, No. 10 - published 01 Mar 2007

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Conformational rigidity of silicon- stereogenic silanes in asymmetric catalysis: A comparative study

Sebastian Rendler, Martin Oestreich

Beilstein J. Org. Chem. 2007, 3, No. 9 - published 08 Feb 2007

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Pd-catalysed [3 + 3] annelations in the stereoselective synthesis of indolizidines

Olivier Y. Provoost, Andrew J. Hazelwood, Joseph P. A. Harrity

Beilstein J. Org. Chem. 2007, 3, No. 8 - published 08 Feb 2007

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Generation of pyridyl coordinated organosilicon cation pool by oxidative Si-Si bond dissociation

Toshiki Nokami, Ryoji Soma, Yoshimasa Yamamoto, Toshiyuki Kamei, Kenichiro Itami, Jun-ichi Yoshida

Beilstein J. Org. Chem. 2007, 3, No. 7 - published 08 Feb 2007

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Tether- directed synthesis of highly substituted oxasilacycles via an intramolecular allylation employing allylsilanes

Peter J. Jervis, Liam R. Cox

Beilstein J. Org. Chem. 2007, 3, No. 6 - published 08 Feb 2007

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Reaction of benzoxasilocines with aromatic aldehydes: Synthesis of homopterocarpans

Míriam Álvarez-Corral, Cristóbal López-Sánchez, Leticia Jiménez-González, Antonio Rosales, Manuel Muñoz-Dorado, Ignacio Rodríguez-García

Beilstein J. Org. Chem. 2007, 3, No. 5 - published 08 Feb 2007

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Contemporary organosilicon chemistry

Steve Marsden

Beilstein J. Org. Chem. 2007, 3, No. 4 - published 08 Feb 2007

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Cimicifoetisides A and B, two cytotoxic cycloartane triterpenoid glycosides from the rhizomes of Cimicifuga foetida, inhibit proliferation of cancer cells

Li-Rong Sun, Chen Qing, Yan-Li Zhang, Shu-Yu Jia, Zhong-Rong Li, Shen-Ji Pei, Ming-Hua Qiu, Michael L. Gross, Samuel X. Qiu

Beilstein J. Org. Chem. 2007, 3, No. 3 - published 31 Jan 2007

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Photosonochemical catalytic ring opening of α-epoxyketones

Hamid R. Memarian, Ali Saffar-Teluri

Beilstein J. Org. Chem. 2007, 3, No. 2 - published 27 Jan 2007

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8-epi-Salvinorin B: crystal structure and affinity at the κ opioid receptor

Thomas A. Munro, Katharine K. Duncan, Richard J. Staples, Wei Xu, Lee-Yuan Liu-Chen, Cécile Béguin, William A. Carlezon Jr., Bruce M. Cohen

Beilstein J. Org. Chem. 2007, 3, No. 1 - published 09 Jan 2007

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Supramolecular chemistry

Thematic Series, edited by Prof. Christoph A. Schalley, Freie Universität Berlin

Progress in liquid crystal chemistry

Thematic Series, edited by Prof. Sabine Laschat, Universität Stuttgart

Chemistry in flow systems

Thematic Series, edited by Prof. Andreas Kirschning, Leibniz Universität Hannover

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